導電高分子於樹脂中聚合行為研究

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Title:	導電高分子於樹脂中聚合行為研究
Other Titles:	Conducting polymer polymerise with epoxy resin
Authors:	林天偉 Lin, Tian-Wei
Contributors:	喬緒明 Chiao, Shu-Min 東海大學化學工程與材料工程學系
Keywords:	電聚合;導電高分子;環氧樹脂 electropolymerize;conducting polymer;epoxy resin
Date:	2011
Issue Date:	2011-10-12T07:52:58Z (UTC)
Abstract:	本研究發現環氧樹脂在丙酮中利用電聚合方式可以成功得到聚合物，在IR的測試中也發現產物確實為環氧樹脂的聚合物，而先前實驗室學長研究中將導電高分子單體加入環氧樹脂中，直接進行電化學聚合，可以得到導電性高分子與環氧樹脂的混合膜，因此本研究是在探討環氧樹脂在加入稀釋劑後，與導電高分子單體進行電化學反應會有何不同的影響。在研究中發現環氧樹脂、電解質和電壓都會影響膜的產率，而且膜的特性也有改變，經SEM的觀察也可以得到完全不同的表面結構，TGA分析也發現不同的條件會有不同的最大裂解溫度，而在混合膜的交流阻抗測試中，可以得到不同的聚合條件，因為聚合速率的改變，造成混合膜的性質有明顯的影響。 The study found that epoxy resin in acetone using electropolymerization method can be successfully obtained polymer. In the IR tests also found that the product does for the epoxy polymer. While the previous laboratory research, we added conductive polymer monomer to epoxy resin. And the direct electrochemical polymerization of conductive polymer can be mixed with the epoxy resin film. This study is to explore what is the electrocmemical reaction different in joining the thinner, epoxy resin and the conductive polymer monomer.Epoxy resin found in the study, the electrolyte membrane and the voltage will affect the yield, but also change the characteristics of film. By SEM observation can also be completely different surface structure. TGA analysis also found that the different conditions have different maximum degradation temperature. While in the mixed membrane impedance test, we can get different result of film which polymerization conditions changes.
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