A [MnIII 3O]7+ single-molecule magnet: The anisotropy barrier enhanced by structural distortion

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题名:	A [MnIII 3O]7+ single-molecule magnet: The anisotropy barrier enhanced by structural distortion
作者:	Yang, C.-I.a, Wernsdorfer, W.b, Cheng, K.-H.a, Nakano, M.c, Lee, G.-H.d, Tsai, H.-L.a
贡献者:	Department of Chemistry, Tunghai University
日期:	2008
上传时间:	2013-05-14T09:02:59Z (UTC)
摘要:	A trinuclear manganese complex, [Mn3O(Me-salox) 3(2,4′-bpy)3-(ClO4)]· 0.5MeCN (1·0.5MeCN; Me-H2salox = 2-hydroxyphenylethanone oxime), has been synthesized and characterized structurally as a [MnIII 3(μ3-O)]7+ core. Structural distortion by the twisting of the oxime ligand dominates ferromagnetic interactions within three Mn ions to give an S = 6 ground state as well as to enhance the anisotropy barrier Ueff to 37.5 K. ? 2008 American Chemical Society.
關聯:	Inorganic Chemistry Volume 47, Issue 22, 17 November 2008, Pages 10184-10186
显示于类别:	[化學系所] 期刊論文

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