Synthesis and characterization of coordination polymers with interpenetrated frameworks: M(adipate)(1,2-bis(4-pyridyl)ethane) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene), M=Co, Mn

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Title:	Synthesis and characterization of coordination polymers with interpenetrated frameworks: M(adipate)(1,2-bis(4-pyridyl)ethane) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene), M=Co, Mn
Authors:	Liao, J.-H.a , Cheng, S.-H.a, Tsai, H.-L.b, Yang, C.-I.b
Contributors:	Department of Chemistry, Tunghai University
Keywords:	Antiferromagnetic;Coordination polymers;Crystal structure;Interpenetrated;Self-assembly
Date:	2002
Issue Date:	2013-05-14T09:03:23Z (UTC)
Abstract:	Four novel coordination polymers: M(adipate)(1,2-bis(4-pyridyl)ethane) (1, 2) and M(adipate)(trans-1,2-bis(4-pyridyl)ethene) (3, 4), M=Co (1, 3) or Mn (2, 4), were synthesized by the self-assembly of Co2+ or Mn2+, adipate, and 1,2-bis(4-pyridyl)ethane or trans-1,2-bis(4-pyridyl)ethene. Their crystal structures were determined by X-ray diffraction, showing that they have similar structures. Each structure of 1-4 contains two sets of interpenetrated open frameworks, which are built by M(adipate) 2-D networks connected by N,N′-dipyridyl ligands. Magnetic studies indicate 1-4 follow Curie-Weiss law and become antiferromagnetic at low temperatures. ? 2002 Elsevier Science B.V. All rights reserved.
Relation:	Inorganica Chimica Acta Volume 338, 14 October 2002, Pages 1-6
Appears in Collections:	[Department of Chemistry ] Periodical Articles

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