Synthesis, spectra and crystal structure of (CO)2(NO)Cr(η5-C5H4)C(O)(η5-C5H4)Fe(η5-C5H5)

Tunghai University Institutional Repository > 理學院 > 化學系所 > 期刊論文 > Item 310901/23469

jsp.display-item.identifier=請使用永久網址來引用或連結此文件: http://140.128.103.80:8080/handle/310901/23469

题名:	Synthesis, spectra and crystal structure of (CO)2(NO)Cr(η5-C5H4)C(O)(η5-C5H4)Fe(η5-C5H5)
作者:	Wang Y.-P., Hwu J.-M., Wang S.-L.
贡献者:	Department of Chemistry, Tunghai University, Taichung, Taiwan;Department of Chemistry, National Tsing Hua University, Tsinchu, Taiwan
日期:	1989
上传时间:	2013-06-24T09:07:52Z (UTC)
摘要:	FriedelCrafts ferrocenoylation of (η5-cyclopentadienyl)dicarbonylnitrosylchromium (10) (hereafter called cynichrodene) has afforded a new metallocenyl ketone ferrocenoylcyclopentadienyldicarbonylnitrosylchromium (7) in 72% yield. The structure of 7 has been solved by an X-ray diffraction study: space group P21/n, a 13.530(3), b 6.387(2), c 18.933(4) ?, β 101.09(2)° and Z = 4. 7 adopts a transoid conformation at the organic carbonyl carbon. The nitrosyl group of the cynichrodenyl moiety is located at the site away from the exocyclic organic carbonyl carbon with a twist angel 177.2°. ? 1989.
關聯:	Journal of Organometallic Chemistry 371
显示于类别:	[化學系所] 期刊論文

文件中的档案:

档案	大小	格式	浏览次数
index.html	0Kb	HTML	198	检视/开启

在THUIR中所有的数据项都受到原著作权保护.